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RESEARCH ARTICLE
Contents Vol 66(8)

Polyoxometalate Insertion into Cu–pz Porous and Cu-bim Knighthead Coordination Polymers: [{Cu4(pz)5.5}{Cu2(2,2′-bim)3}0.5{P2W18O62}]·H2O

Yanglei Xu A B , Jiang Wu A B , Kai Yu A B , Zhanhua Su A B , Chunxiao Wang A B , Chunmei Wang A B and Baibin Zhou A B C
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Heilongjiang Province, Harbin Normal University, Harbin, 150025, China.

B Key Laboratory for Photonic and Electronic Band Gap Materials, Ministry of Education, Harbin Normal University, Harbin, 150025, China.

C Corresponding author. Email: zhou_bai_bin@163.com

Australian Journal of Chemistry 66(8) 938-943 https://doi.org/10.1071/CH13111
Submitted: 7 March 2013  Accepted: 28 April 2013   Published: 17 May 2013

Abstract

The structure of crystallised {[Cu4(pz)5.5][Cu2(2,2′-bim)3]0.5[P2W18O62]}·H2O (1) (pz = pyrazine, bim = biimidazole) is reported. The crystal structure is characterised by cage-like pores [Cu8(pz)11]8+ of Cu ions linked through pz ligands. [P2W18O62]6– polyanions are capsulated into cage-like pores of [Cu8(pz)11]8+, forming ‘hamburger’-like units. Furthermore, the three-dimensional framework in 1 is achieved via copper-pyrazolate layers, binuclear copper-biimidazole subunits, and Dawson-type polyoxometalate clusters. The electrochemical properties of compound 1 were also studied in detail.


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