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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
REVIEW

A Review of Catalytic Systems for Glycerol Oxidation: Alternatives for Waste Valorization

Juan Carlos Beltrán-Prieto A B , Karel Kolomazník A and Jiří Pecha A
+ Author Affiliations
- Author Affiliations

A Department of Automation and Control Engineering, Faculty of Applied Informatics, Tomas Bata University in Zlín, nám. T. G. Masaryka 5555, 760 01 Zlín, Czech Republic.

B Corresponding author. Email: prieto@fai.utb.cz




Juan Carlos Beltrán Prieto obtained his bachelor’s and master’s degrees in biochemical engineering from the Technological Institute of Celaya (México). He is currently a third-year Ph.D. student in the research group of Professor Karel Kolomazník. His research is focused on mathematical optimisation, catalytical systems, and hazardous waste treatment technologies.



Professor Karel Kolomazník is a chemical engineer working in the field of leather processing and waste utilisation. He is a laureate of the Rolex Award for Enterprise, for the development of technology for processing and recycling of potentially hazardous chrome-tanned waste produced by the leather industry.



Jiří Pecha is a chemical engineer, with a master’s degree in polymer processing from Tomas Bata University in Zlin. His research interests cover processing of waste fats and oils into biodiesel and glycerine, process development, and mathematical simulations. He is presently working as a researcher at Tomas Bata University in Zlin.

Australian Journal of Chemistry 66(5) 511-521 https://doi.org/10.1071/CH12514
Submitted: 6 November 2012  Accepted: 15 February 2013   Published: 14 March 2013

Abstract

Endeavours leading to the study of glycerol oxidation result from the imperative necessity for wise utilization of surplus glycerine generated as by-product from biodiesel manufacture. The oxidation of glycerol is one of the most promising reactions as it leads to the generation of valuable glycerol derivatives that find broad application in pharmaceutical, polymer, and food industries. This review highlights the processing alternatives for glycerol by means of biocatalyst-mediated, heterogeneous, homogeneous, and electrochemical oxidation. The current state of the art is evaluated and recommendations for further research and future directions are included.


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