Three-Membered Metal-Nucleobase-Carboxylate System Showing Interesting 2D and 3D Architecture: Synthesis, Structure, Thermostability, and Magnetic Properties
Hai-Xiao Huang A , Xiao-Zhao Tian A , Yu-Mei Song A , Zhen-Wei Liao A , Gong-Ming Sun A , Ming-Biao Luo A , Shu-Juan Liu A , Wen-Yuan Xu A and Feng Luo A B
+ Author Affiliations
- Author Affiliations
A College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, Jiangxi 344000, P. R. China.
B Corresponding author. Email: ecitluofeng@163.com
Australian Journal of Chemistry 65(3) 320-325 https://doi.org/10.1071/CH11404
Submitted: 20 October 2011 Accepted: 21 December 2011 Published: 2 February 2012
Abstract
Via hydrothermal synthesis, we constructed four nucleobase metal-organic compounds, viz. Zn2(7H-ade)(oba)2·H2O (1), Zn(1H-hyp)(Hoba) (2), Ni(1H-ade)(ip) (3), and Cd(H2O)(9H-ade)(ip) (4), where ade, hyp, H2oba, and H2ip are adenine, hypoxanthine, 4,4′-oxybisbenzoic acid, and isophthalic acid, respectively. These polymers show novel 2D and 3D structures, such as 3-fold interpenetrating dmp net, supramolecular zeolite-type sra net, and exceptional 2D 44 net composed of three kinds of quadrangle, observed in polymers 1, 2, and 3, respectively. Moreover, thermogravimetric studies of polymers 1, 2, and 4, and the magnetic properties of 3 are also explored.
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