A Mass-Sensitive Approach for the Detection of Anaesthetic Xenon*
Oliver Hayden A , Usman Latif A and Franz L. Dickert A B
+ Author Affiliations
- Author Affiliations
A Department of Analytical Chemistry, University of Vienna, Waehringerstrasse 38, A–1090 Vienna, Austria.
B Corresponding author. Email: franz.dickert@univie.ac.at
Australian Journal of Chemistry 64(12) 1628-1632 https://doi.org/10.1071/CH11267
Submitted: 1 July 2011 Accepted: 23 August 2011 Published: 15 September 2011
Abstract
Quartz crystal microbalances (QCMs) were utilized for the detection of the noble gas xenon (Xe) by combining them with different recognition layers such as permethylated calixarenes (tetramethyl-tert-butylcalix[4]arene (Cal4Me), hexamethyl-tert-butylcalix[6]arene (Cal6Me)), and polyurethanes, with covalently embedded Cal4OH (Poly4Cal), or Cal6OH (Poly6Cal). A third type of sensitive material is synthesized from polyacrylic acid (PAA) and polyvinyl alcohol (PVA) and utilized as a sensitive coating. The results demonstrate that the Cal4Me layer gives higher response towards Xe, while, by the use of a second uncoated QCM channel, the influence of ambient humidity could be nearly completely compensated by signal subtraction. Moreover, the Cal4Me sensor shows excellent reversibility and rapid response time, providing a potentially reliable way to determine Xe during anaesthesia.
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