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RESEARCH ARTICLE
Contents Vol 64(7)

Porphyrin–Phosphoramidate Conjugates: Synthesis, Photostability and Singlet Oxygen Generation

Leandro F. Pedrosa A B , Marcos C. de Souza B , Maria A. F. Faustino A , Maria G. P. M. S. Neves A , Artur M. S. Silva A , Augusto C. Tomé A , Vitor F. Ferreira B and José A. S. Cavaleiro A C
+ Author Affiliations
- Author Affiliations

A Department of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal.

B Departamento de Química Orgânica, Universidade Federal Fluminense, 24020-141 Niterói, Rio de Janeiro, Brazil.

C Corresponding author. Email: jcavaleiro@ua.pt

Australian Journal of Chemistry 64(7) 939-944 https://doi.org/10.1071/CH11013
Submitted: 7 January 2011  Accepted: 29 March 2011   Published: 19 July 2011

Abstract

meso-Tetrakis(pentafluorophenyl)porphyrin reacts with aminoalkylphosphoramidates to afford porphyrins substituted with one or four phosphoramidate groups in the 4-position of the meso-aryl groups. The new porphyrin derivatives show high photostability and some are better singlet oxygen generators than meso-tetrakis(1-methylpyridinium-4-yl)porphyrin, a well known good singlet oxygen producer.


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