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RESEARCH ARTICLE
Contents Vol 64(10)

A Series of 2D and 3D Novel Lanthanide Complexes Constructed from Squarate C4O42–: Syntheses, Structures, Magnetic Properties, and Near-infrared Emission Properties

Li Wang A , Wen Gu A B C , Xiu-Jun Deng A , Ling-Fei Zeng A , Sheng-Yun Liao A , Ming Zhang A , Lin-Yan Yang A and Xin Liu A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Nankai University, Tianjin 300071, China.

B Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China.

C Corresponding author. Email: guwen68@nankai.edu.cn

Australian Journal of Chemistry 64(10) 1373-1382 https://doi.org/10.1071/CH10459
Submitted: 15 December 2010  Accepted: 31 May 2011   Published: 23 August 2011

Abstract

The solvothermal combination of trivalent lanthanide metal precursors with a squarate ligand (H2C4O4, 3,4-dihydroxy-3-cyclobutene-1,2-dione) has afforded the preparation of a family of eight new coordination polymers, [Ln2(C4O4)3(H2O)4] (Ln = La–Nd, Ho) (1–5), [Ln2(C4O4)3(H2O)8] (Ln = Er, Dy) (6, 7), and Tb2(C4O4)2(C2O4)(H2O)4 (8). Structural analysis reveals that the squarate ligand displays versatile coordination modes to generate novel 2D and 3D frameworks. Three new coordination modes, a bidentate/monodentate μ3 and two bidentate/monodentate μ4 coordination modes, are first reported. In addition, the variable-temperature magnetic properties of the Pr, Nd, Ho, Dy, and Tb complexes, the solid-state near-infrared luminescence spectra of the Pr, Nd, Ho, and Er complexes, and their thermogravimetric analyses are discussed.


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