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RESEARCH ARTICLE
Contents Vol 64(2)

Copper(ii) Complexes with cis-Epoxysuccinate Ligand: Syntheses, Crystal Structures, and Magnetic Properties

Shao-Ming Fang A C , E. Carolina Sañudo B , Min Hu A , Qiang Zhang A , Li-Ming Zhou A and Chun-Sen Liu A C
+ Author Affiliations
- Author Affiliations

A Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou, Henan 450002, China.

B Institut de Nanociència i Nanotecnologia i Departament de Química Inorgànica, Universitat de Barcelona, Diagonal, 647, 08028-Barcelona, Spain.

C Corresponding authors. Email: chunsenliu@zzuli.edu.cn, smfang@zzuli.edu.cn

Australian Journal of Chemistry 64(2) 217-226 https://doi.org/10.1071/CH10371
Submitted: 10 October 2010  Accepted: 5 January 2011   Published: 15 February 2011

Abstract

Three CuII complexes with cis-epoxysuccinate ligand were synthesized and structurally characterized: [Cu(ces)(phen)]2 (1), [Cu(ces)(bpy)]2 (2), and {[Cu2(ces)(pp)2(CH3OH)]}∞ (3), (ces = cis-epoxysuccinate, phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine, and pp = 3-(2-pyridyl)pyrazole with pyrazolyl N-donor deprotonated). Structural analysis reveals that both 1 and 2 have the very similar dinuclear units that are extended by the intermolecular supramolecular interactions, such as C–H⋯O, C–H⋯π, and aromatic π⋯π stacking interactions, to give rise to the higher-dimensional frameworks. Complex 3 has a two-dimensional (2D) layered structure that is further assembled to form a three-dimensional framework by the inter-layer C–H⋯O hydrogen-bonding and C–H⋯π interactions. A structural comparison with those of our previous work in the absence of auxiliary co-ligand suggests that the introduction of 2,2′-bipyridyl-like molecules plays an important role in constructing the final structures of 1–3. Magnetic measurements demonstrate that 1 and 2 exhibit ferromagnetic coupling with the corresponding J values of 1.8 cm–1 for 1 and 1.5 cm–1 for 2, whereas 3 shows more complicated magnetic coupling.


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