Controlled Dispersion Polymerization in Supercritical Carbon Dioxide
Kristofer J. Thurecht A B and Steven M. Howdle A CA School of Chemistry, University of Nottingham, NG7 2RD, Nottingham, UK.
B Current address: Australian Institute for Bioengineering and Nanotechnology and Centre for Magnetic Resonance, University of Queensland, St Lucia, Qld 4072, Australia.
C Corresponding author. Email: steve.howdle@nottingham.ac.uk
Australian Journal of Chemistry 62(8) 786-789 https://doi.org/10.1071/CH09081
Submitted: 10 February 2009 Accepted: 15 April 2009 Published: 13 August 2009
Abstract
Recent advances in controlled polymerization have led to increased activity in controlled free radical polymerization in unconventional solvents. This short report focuses on the renewed interest in dispersion polymerization in supercritical CO2 brought about by the application of controlled free radical polymerization techniques. The emergence of novel and industrially-applicable materials is discussed, as well as the dependence of material properties and morphology upon factors such as surfactant type and how it is employed during the polymerization.
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