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Contents Vol 62(3)

Microwave-Assisted Ruthenium-Catalyzed Reactions

François Nicks A , Yannick Borguet A , Sébastien Delfosse A , Dario Bicchielli A , Lionel Delaude A , Xavier Sauvage A and Albert Demonceau A B
+ Author Affiliations
- Author Affiliations

A Laboratory of Macromolecular Chemistry and Organic Catalysis, University of Liège, Sart-Tilman (B.6a), B-4000 Liège, Belgium.

B Corresponding author. Email: a.demonceau@ulg.ac.be




From left to right: Albert Demonceau, François Nicks, Xavier Sauvage, Yannick Borguet, Dario Bicchielli, Sébastien Delfosse, Lionel Delaude.

Australian Journal of Chemistry 62(3) 184-207 https://doi.org/10.1071/CH08510
Submitted: 20 November 2008  Accepted: 16 February 2009   Published: 20 March 2009

Abstract

Since the first reports on the use of microwave irradiation to accelerate organic chemical transformations, a plethora of papers has been published in this field. In most examples, microwave heating has been shown to dramatically reduce reaction times, increase product yields, and enhance product purity by reducing unwanted side reactions compared with conventional heating methods. The present contribution aims at illustrating the advantages of this technology in homogeneous catalysis by ruthenium complexes and, when data are available, at comparing microwave-heated and conventionally heated experiments. Selected examples refer to olefin metathesis, isomerization reactions, 1,3-dipolar cycloadditions, atom transfer radical reactions, transfer hydrogenation reactions, and H/D exchange reactions.


Acknowledgements

The authors gratefully acknowledge the ‘Fonds National de la Recherche Scientifique’ (FNRS), Brussels, and the ‘Fonds Spéciaux pour la Recherche’ (University of Liège) for the purchase of a microwave reactor. The authors also thank the ‘Fonds pour la Formation à la Recherche dans l’Industrie et dans l’Agriculture’ (FRIA) for a fellowship to F. Nicks and D. Bicchielli.


References


[1]   (a) For some recent monographs on microwave-assisted reactions, see: Hayes B. L., Microwave Synthesis: Chemistry at the Speed of Light, 1st edn 2002 (CEM Publishing: Matthews, NC).
       (b) Kappe C. O., Stadler A., Microwaves in Organic and Medicinal Chemistry 2005 (Wiley-VCH: Weinheim).
       (c) Microwaves in Organic Synthesis, 2nd edn (Ed. A. Loupy) 2006 (Wiley-VCH: Weinheim).

[2]   (a) For some recent reviews on microwave-assisted reactions, see: Perreux L., Loupy A., Tetrahedron 2001, 57, 9199. doi:10.1016/S0040-4020(01)00905-X
       (b) P. Lidström, J. Tierney, B. Wathey, J. Westman, Tetrahedron 2001, 57,  9225.
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