Rapid Synthesis of O,O′-Dialkyl Alkylphosphonates on TLC with Analytical Purity for the Verification Analysis of Chemical Weapons Convention

Hemendra K. Gupta; Deepak Pardasani; Arvind K. Gupta; Rajiv Jain; D. K. Dubey

doi:10.1071/CH07426

RESEARCH ARTICLE

Previous Next Contents Vol 61(5)

Rapid Synthesis of O,O′-Dialkyl Alkylphosphonates on TLC with Analytical Purity for the Verification Analysis of Chemical Weapons Convention

Hemendra K. Gupta ^A , Deepak Pardasani ^A , Arvind K. Gupta ^A , Rajiv Jain ^B and D. K. Dubey ^A ^C

+ Author Affiliations

- Author Affiliations

^A Vertox Laboratory, Defence Research and Development Establishment, Gwalior 470002, India.

^B School of Studies Chemistry, Jiwaji University, Gwalior, India.

^C Corresponding author. Email: dkdubey@rediffmail.com

Australian Journal of Chemistry 61(5) 324-328 https://doi.org/10.1071/CH07426
Submitted: 11 December 2007 Accepted: 28 March 2008 Published: 22 May 2008

Abstract

Reaction parameters for the rapid synthesis of O,O′-dialkyl alkylphosphonates and O-alkyl hydrogen alkylphosphonates were optimized using thin-layer chromatographic plates as a solid-supported platform under microwave irradiation. Immediate synthesis of these compounds with analytical purity is of paramount importance for the verification analysis of the Chemical Weapons Convention.

References

Rapid Synthesis of O,O′-Dialkyl Alkylphosphonates on TLC with Analytical Purity for the Verification Analysis of Chemical Weapons Convention

Abstract

Subscriber Login