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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Functionalization of Baylis–Hillman Bromides with Symmetric and Asymmetric Bifunctional Aromatics

Yusuf Zulykama A and Paramasivan T. Perumal A B
+ Author Affiliations
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A Organic Chemistry Division, Central Leather Research Institute, Adyar, Chennai-20, India.

B Corresponding author. Email: ptperumal@gmail.com

Australian Journal of Chemistry 60(3) 205-210 https://doi.org/10.1071/CH06342
Submitted: 19 September 2006  Accepted: 23 February 2007   Published: 2 April 2007

Abstract

Nucleophilic substitution products of Baylis–Hillman adducts are valuable synthons. In an attempt to improve the functionality of Baylis–Hillman adducts we report the regio- and chemo-selective fuctionalization of Baylis–Hillman bromides with symmetric and asymmetric bifunctional aromatics.


Acknowledgment

Y.Z. thanks CSIR, India, for financial support.


References


[1]   (a) S. E. Drewes, G. H. P. Roos, Tetrahedron 1988, 44,  4653.
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