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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Synthesis and Complexes of the New Scorpionate Ligand Tris[3-(4-benzonitrile)-pyrazol-1-yl]borate

Stuart R. Batten A B , Martin B. Duriska A , Paul Jensen A and Jinzhen Lu A
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A School of Chemistry, Monash University, Clayton VIC 3800, Australia.

B Corresponding author. Email: stuart.batten@sci.monash.edu.au

Australian Journal of Chemistry 60(1) 72-74 https://doi.org/10.1071/CH06329
Submitted: 5 September 2006  Accepted: 6 December 2006   Published: 29 January 2007

Abstract

A new scorpionate ligand, hydro-tris[3-(4-benzonitrile)-pyrazol-1-yl]borate (Tp4bz), was synthesized and the crystal structures of its potassium salt and its MnII, CoII, NiII, and CdII complexes were determined.


Acknowledgment

This work was supported by The Australian Research Council.


References


[1]   (a) S. Trofimenko, Scorpionates: The Coordination Chemistry of Poly(pyrazolyl)borate Ligands 1999 (Imperial College Press: London).
       (b) C. Pettinari, C. Santini, Comp. Coord. Chem. II 2004, 1,  159.
         
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