The 3-Hydroxycineoles

Raymond M. Carman; Ward T. Robinson; Craig J. Wallis

doi:10.1071/CH05144

RESEARCH ARTICLE

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The 3-Hydroxycineoles

Raymond M. Carman ^A ^C , Ward T. Robinson ^B and Craig J. Wallis ^A

+ Author Affiliations

- Author Affiliations

^A Chemistry, University of Queensland, Brisbane QLD 4072, Australia.

^B Department of Chemistry, University of Canterbury, Christchurch, New Zealand.

^C Corresponding author. Email: carman@chemistry.uq.edu.au

Australian Journal of Chemistry 58(11) 785-791 https://doi.org/10.1071/CH05144
Submitted: 20 June 2005 Accepted: 21 September 2005 Published: 9 December 2005

Abstract

Data concerning the 3-hydroxycineoles 1 and 2 are provided to enable the ready identification of these metabolites and to determine their enantiomeric excess in mixtures. An unusual S_N2-type inversion at a tertiary center is observed during one synthetic approach.

Acknowledgment

We thank Tommy Karoli for early investigations into these systems.

References

^* We thank a referee for discussion on this point.

The 3-Hydroxycineoles

Abstract

Acknowledgment

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