A Three-Dimensional Silver(i) Framework Assembled from Nitrilotriacetate

Chun-Long Chen; Qian Zhang; Ji-Jun Jiang; Qin Wang; Cheng-Yong Su

doi:10.1071/CH04243

RESEARCH ARTICLE

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A Three-Dimensional Silver(i) Framework Assembled from Nitrilotriacetate

Chun-Long Chen ^A , Qian Zhang ^A , Ji-Jun Jiang ^A , Qin Wang ^A and Cheng-Yong Su ^A ^B ^C

+ Author Affiliations

- Author Affiliations

^A School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

^B State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.

^C Corresponding author. Email: cedc63@zsu.edu.cn

Australian Journal of Chemistry 58(2) 115-118 https://doi.org/10.1071/CH04243
Submitted: 9 October 2004 Accepted: 18 December 2004 Published: 21 February 2005

Abstract

The reaction of AgCF₃CO₂ with nitrilotriacetate (NTA) yields the three-dimensional silver(i) coordination polymer {Ag₃[N(CH₂COO)₃]}_n 1 which was characterized by means of elemental analysis and IR spectroscopy as well as X-ray diffraction. The single crystal structure shows that the NTA^3– anions act as unusual heptadentate 13-coordination agents and the silver(i) atoms exhibit various coordination numbers in the range 3–6.

Acknowledgments

We thank Funds of the State Key Laboratory of Structural Chemistry in Fujian Institute of Research on the Structure of Matter, the Natural Science Foundations of China (nos. 20303027 and 20131020), and the Research Fund for the Doctoral Program of Higher Education.

References

A Three-Dimensional Silver(i) Framework Assembled from Nitrilotriacetate

Abstract

Acknowledgments

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