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Recent Advances in Luminescent Monomeric, Multinuclear, and Polymeric Zn(ii) and Cd(ii) Coordination Complexes

Shao-Liang Zheng ^A and Xiao-Ming Chen ^A ^B

+ Author Affiliations

- Author Affiliations

^A School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

^B Author to whom correspondence should be addressed (e-mail: cescxm@zsu.edu.cn).

Australian Journal of Chemistry 57(8) 703-712 https://doi.org/10.1071/CH04008
Submitted: 19 January 2004 Accepted: 26 May 2004 Published: 10 August 2004

Abstract

‘Luminescence research has a long history full of splendor and surprise, and a bright future, promising variegated applications to probe molecules and crystals, to visualize atomic phenomena, …’ H. J. Queisser, 1981

This article briefly summarizes recent progress on the luminescence studies of monomeric, multinuclear, and polymeric Zn(ii)/Cd(ii) coordination complexes, involving spectroscopic, photophysical, and photochemical studies, as well as molecular and electronic structural investigations, focussing mainly on the interplaying factors that govern the luminescent origin of the lowest-lying emissive states. Current results show that, for Zn(ii)/Cd(ii) coordination complexes in general, the nature of the metal centres and ligands and the rigid metal-oxy (or -hydroxy) clusters are factors governing their luminescent origin of the lowest-lying emissive states; different types of ligands and coordination structures may result in different emission mechanisms.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (grant no. 20131020), the Ministry of Education of China (grant no. 01134), and the Scientific and Technological Project of Guangdong Province.

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