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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Keto–Enol Tautomerism as a Polarity Indicator in Ionic Liquids

Martyn J. Earle, Brian S. Engel and Kenneth R. Seddon

Australian Journal of Chemistry 57(2) 149 - 150
Published: 02 February 2004

Abstract

The keto–enol tautomeric equilibrium for pentane-2,4-dione has been explored in several ionic liquids and these data have been used to give an indication of their polarities in the ground state. The results suggest higher apparent polarities than have been previously indicated by the use of solvatochromatic dyes.

Keywords: ground state — ionic liquids — pentane-2,4-dione — polarity — tautomerization

https://doi.org/10.1071/CH03259

© CSIRO 2004

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