Ionic Liquids Based on Imidazolium and Pyrrolidinium Salts of the Tricyanomethanide Anion

Abstract

A novel series of tricyanomethanide ionic liquids have been prepared and characterized for potential use as ionic liquid solvents. Full thermal analyses of all salts at ambient and sub-ambient temperatures are reported (melting points –17° to 160°C). The thermal stability and decomposition temperatures are also presented (T_decomp ≈ 300°C). An electrochemical window of ~3 V has been established and the conductivity measured over a range of temperatures (20 mS cm^–1 at 25°C).