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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Towards the Synthesis of Aureolic Acid Analogue Conjugates: Synthesis and Glycosidation Reactions of 3-O-Acetyl-4-azido-2,4,6-trideoxy-L-glucopyranose Derivatives

W. R. Roush and R. A. James

Australian Journal of Chemistry 55(2) 141 - 146
Published: 05 June 2002

Abstract

A stereoselective synthesis of 3-O-acetyl-4-azido-glucopyranose (6) is described. The derived anomeric acetate (13), and especially the thioglycoside (14), are demonstrated to be good donors for synthesis of α-glycosides of (6). Donor (14) was used in the synthesis of trisaccharide (21), which is targeted for use in the synthesis of the aureolic acid trisaccharide conjugate analogue (5).

https://doi.org/10.1071/CH01199

© CSIRO 2002

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