Synthesis, Characterization, and Modelling of Novel Multifunctional Acryloyl-Based Monomers: An Experimental and Computational Study
Georgia Patras, Greg G. Qiao,
David H. Solomon and Rainer Koch
Australian Journal of Chemistry
55(10) 675 - 680
Published: 15 November 2002
Abstract
Several novel multifunctional monomers with at least three reactive N-acryloyl double bonds have been synthesized and fully characterized. Quantum-chemical calculations and nuclear magnetic resonance (NMR) spectroscopy have been used to predict the structural dissymmetry of these monomers: the simulation of conformers and the NMR spectrum of monomer (3) allows the explanation of the observed 13C NMR spectra as well as a comparison of the performance of several methods for calculating chemical shifts.https://doi.org/10.1071/CH01082
© CSIRO 2002