Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

X-Ray Study of Two ZnII and CdII 2,2'-Dipyridylamine Thiosulfate Compounds

Eleonora Freire, Sergio Baggio, álvaro Mombrú and Ricardo Baggio

Australian Journal of Chemistry 54(3) 193 - 197
Published: 2001

Abstract

Two ZnII and CdII thiosulfato(2,2′-dipyridylamine) complexes, namely [Zn2(S2O3)2(dpa)3·H2O]·H2O (1) and [Cd(S2O3)(dpa)(H2O)] (2) (dpa = 2,2′-dipyridylamine), have been prepared and their crystal structures determined and compared with related structures in the literature. Compound (1) is triclinic P1, a 10.170(3), b 12.821(3), c 14.899(3) Å, α 108.33(2), β 90.34(2), γ 109.02(2)˚, V 1730.7(7) Å3, Z 2, conventional R (on F) being 0.031 for 6379 No observed reflections (I >2σ (I)). Compound (2) is monoclinic, P21/c, a 9.897(3), b 19.235(4), c 7.205(1) Å, ‚ 101.48(7)˚, V 1344.2(4) Å3, Z 4, R 0.032, No 2494.

https://doi.org/10.1071/CH01029

© CSIRO 2001

Committee on Publication Ethics


Export Citation Get Permission

View Dimensions