Reducing phosphorus leaching from sandy soils with red mud bauxite processing residues

Abstract

This study used field lysimeters to investigate the reduction in the leaching of phosphorus (P) applied as superphosphate fertilizer from a very sandy Swan Coastal Plain soil treated with bauxite processing residue (red mud) neutralized with either waste gypsum from the phosphate industry or ferrous sulfate (copperas) from the titanium dioxide industry. Addition of 500 t ha-' red mud/gypsum or 200 t hap1 red mud/copperas were found to reduce the leaching of P to below 3 kg ha-l for application rates of 270 and 80 kgP ha-1, respectively. Water retention from these excessively well drained soils was increased by 14 and 50% by the addition of 200 and 2000 t ha-l red mud, respectively. The pH of the leachate for all rates of red mud/copperas application increased from approximately 4 to range between 7 and 7-5. The concentrations of Na and SO4 were about 8 and 17 g1-l, respectively, in the initial leachates collected from the 2000 t ha-' red mud treatment but declined to approximately 0.4 and 2.0g l-1 after 3 years of leaching. The Ca leaching appeared to be initially controlled by the solubility of the excess CaSO4 remaining after red mud neutralization, with concentrations ranging between 0.3 and 0.5 g l-1 before declining to approximately the levels for untreated soils of 0.01-0.06g l-1. The Na, So4 and Ca concentrations in the leachates from the 500 t ha-l red mud/copperas treated soil decreased to acceptable levels after 2 years. High total soluble salt (TSS) levels associated with high levels of residue application may affect pasture production in the years immediately following soil amendment