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RESEARCH ARTICLE
Contents Vol 44(3)

Effects of modified clinoptilolite on phosphorus mobilisation and potassium or ammonium release in Ferrosols

Q. X. Hua A B , J. M. Zhou A D , H. Y. Wang A , C. W. Du A , X. Q. Chen A and J. Y. Li C
+ Author Affiliations
- Author Affiliations

A State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, 71 East Beijing Road, Nanjing 210008, P.R. China.

B Graduate School of Chinese Academy of Science, 19 Yuquan Road, Beijing 100049, P. R. China.

C Department of Industrial Engineering, Zhengzhou Institute of Aeronautical Industry Management, 2 Daxue Road, Zhengzhou 450015, P.R. China.

D Corresponding author. Email: jmzhou@issas.ac.cn

Australian Journal of Soil Research 44(3) 285-290 https://doi.org/10.1071/SR05118
Submitted: 22 August 2005  Accepted: 20 February 2006   Published: 5 May 2006

Abstract

An investigation was conducted to study effects of the potassium and ammonium saturated clinoptilolite on P availability in Ferrosols. The adsorption and desorption of phosphorus were determined by shaking 2.5 g soil with 0, 0.5, and 2.5 g clinoptilolite at 0.31 or 1.25 mg P/g soil in 50 mL solution for a total of 72 h (24 h for clinoptilolite and 48 h for phosphate). The nutrient concentrations in supernatants were measured by spectrophotometry. Results showed phosphorus solubility was significantly increased with clinoptilolite addition. Increasing the amount of clinoptilolite enhanced the concentration of P up to 6.85 and 41.29 mg/L at 0.31 and 1.25 mg P/g soil, respectively. Correspondingly, the amount of potassium and ammonium released from the clinoptilolite were up to 63.69 and 12.20 mg/L at 0.31 mg P/g soil, and 107.42 and 29.94 mg/L at 1.25 mg P/g soil. Nutrient concentrations in the treatments in which clinoptilolite was added before P were greater than that in the treatments in which P was added prior to clinoptilolite. The results also suggest that potassium and ammonium saturated clinoptilolite can increase P solubility while providing K and NH4 to the soil, a concurrent positive effect for plant growth.

Additional keywords: clinoptilolite, Ferrosols, phosphate, potassium, ammonium.


Acknowledgments

This research was funded by the National Natural Foundation of China (No. 30400273) and Potassium & Phosphate Institute/Potassium & Phosphate Institute of Canada (PPI/PPIC). The authors thank Professor Keith WT Goulding for revising this paper.


References


Aleksandrova VS, Zykova OP, Markiv EY (2004) Ion-exchange properties and IR spectra of natural clinoptilolite modified with titanium hydroxophosphates. Russian Journal of Applied Chemistry 77, 30–33.
| Crossref | GoogleScholarGoogle Scholar | open url image1

Allen ER, Hossner LR, Ming DW, Henninger DL (1993) Solubility and cation exchange in phosphate rock and saturated clinoptilolite mixtures. Soil Science Society of America Journal 57, 1368–1374.
| PubMed |
open url image1

Allen ER, Hossner LR, Ming DW, Henninger DL (1996) Release rates of phosphorus, ammonium, and potassium in clinoptilolite-phosphate rock systems. Soil Science Society of America Journal 60, 1467–1472. open url image1

Allen ER, Ming DW, Hossner LR, Henninger DL (1995a) Modeling transport kinetics in clinoptilolite-phosphate rock system. Soil Science Society of America Journal 59, 248–255.
| PubMed |
open url image1

Allen ER, Ming DW, Hossner LR, Henninger DL, Galindo C (1995b) Growth and nutrient uptake of wheat in clinoptilolite-phosphate rock substrates. Agronomy Journal 87, 1052–1059. open url image1

Armbruster T (2001) Clinoptilolite-heulandite: applications and basic research. In ‘Studies in surface science and catalysis 135. Zeolite and mesoporous materials at the dawn of the 21st Century’. (Eds A Galarnau, FD Renzo, F Faujula, J Vedrine) pp. 13–27. (Elsevier: New York)

Barbarick KA, Lai TM, Eberl DD (1990) Exchange fertilizer (phosphate rock plus ammonium-zeolite) effects on sorghum-sudangrass. Soil Science Society of America Journal 54, 911–916. open url image1

Chu HY, Zhu JG, Xie ZB, Zeng Q, Li ZG, Cao ZH (2003) Availability and toxicity of exogenous lanthanum in a haplic acrisols. Geoderma 115, 121–128.
| Crossref |
open url image1

CRGCST (2001) ‘Chinese Soil Taxonomy.’ (Science Press: Beijing)

Du ZY, Zhou JM, Wang HY, Du CW, Chen XQ (2005) Effect of nitrogen fertilizers on movement and transformation of phosphorus in an acid soil. Pedosphere 15, 424–431. open url image1

Ferguson GA, Pepper IL, Kneebone WR (1986) Growth of creeping bentgarss on a new medium for turfgrass growth: clinoptilolite zeolite-amended sand. Agronomy Journal 78, 1095–1098. open url image1

Goh TB, Pawluk S, Dudas MJ (1986) Adsorption and release of phosphate in chernozemic and solodized solonetzic soils. Canadian Journal of Soil Science 66, 521–529. open url image1

He ZL, Baligar VC, Martens DC, Ritchey KD, Elrashidi M (1999) Effect of byproduct, nitrogen fertilizer, and zeolite on phosphate rock dissolution and extractable phosphorus in acid soil. Plant and Soil 208, 199–207.
| Crossref | GoogleScholarGoogle Scholar | open url image1

Inglezakis VJ, Loizidou MM, Grigoropoulou HP (2002) Equilibrium and kinetic ion exchange studies of Pb, Cr, Fe and Cu on natural clinoptilolite. Water Research 36, 2784–2792.
| Crossref | GoogleScholarGoogle Scholar | PubMed | open url image1

Inglezakis VJ, Loizidou MM, Grigoropoulou HP (2004) Ion exchange studies on natural and modified zeolites and the concept of exchange site accessibility. Journal of Colloid and Interface Science 275, 570–576.
| Crossref | GoogleScholarGoogle Scholar | PubMed | open url image1

Keeney DR , Nelson DW (1982) Nitrogen-inorganic forms. In ‘Methods of soil analysis. Part 2. Chemical and microbiological properties’. (Eds AL Page, RH Miller, DR Keeney) pp. 643–698. (ASA and SSSA Publishing: Madison, WI)

Li ST, Zhou JM, Wang HY, Du CW, Chen XQ (2005) Kinetics of phosphate release from three phosphate-treated soils. Pedosphere 15, 518–525. open url image1

Lu RK (1999) ‘Methods of soil and agrochemistry analysis.’ (Publishing House of Agricultural Science and Technology in China: Beijing)

Mcbeath TM, Armstrong RD, Lombi E, Mclaughlin MJ, Holloway RE (2005) Responsiveness of wheat (Triticum aestivum) to liquid and granular phosphorus fertilisers in southern Australian soils. Australian Journal of Soil Research 43, 203–212.
| Crossref | GoogleScholarGoogle Scholar | open url image1

Olsen SR , Sommers LE (1982) Phosphorus. In ‘Methods of soil analysis. Part 2. Chemical and microbiological properties’. (Eds AL Page, RH Miller, DR Keeney) pp. 403–430. (ASA and SSSA Publishing: Madison, WI)

Opena GB, Williams KA (2003) Use of precharged zeolite to provide aluminum during blue hydrangea production. Journal of Plant Nutrition 26, 1825–1840.
| Crossref | GoogleScholarGoogle Scholar | open url image1

Ozanne PG (1980) Phosphate nutrition of plants—a general treatise. In ‘The role of phosphorus in agriculture’. (Eds FE Khasawneh, EC Sample, EJ Kamprath) pp. 559–590. (ASA, CSSA and SSSA Publishing: Madison, WI)

Pickering HW, Menzies NW, Hunter MN (2002) Zeolite/rock phosphate—a novel slow release phosphorus fertilizer for potted plant production. Scientia Horticulturae 94, 333–343.
| Crossref | GoogleScholarGoogle Scholar | open url image1

Polat E, Karaca M, Demir H, Onus AN (2004) Use of natural zeolite (clinoptilolite) in agriculture. Journal of Fruit and Ornamental Plant Research 12, 183–189. open url image1