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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
Australian Journal of Chemistry

Australian Journal of Chemistry

Volume 73 Number 7 2020

CH19400The Host–Guest Properties Observed Between the Viologens and Cyclopentanocucurbit[6]uril

Si-Yuan Cheng, Yun-Xia Qu, Zhu Tao, Kai-Zhi Zhou, Lian-Tong Wei, Cong Wang, Wei-Wei Zhao, Dao-Fa Jiang and Pei-Hua Ma 0000-0002-0572-9461
pp. 601-607
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Although the host–guest chemistry of cucurbit[n]urils continues to flourish, that of the related cyclopentanocucurbit[6]uril (CyP6Q[6]) is at an embryonic stage. We are interested in the ability of CyP6Q[6] to include viologens, CyP6Q[6] shows many interesting and different properties, compared with other cucurbit[n]urils (Q[n]s) and their derivatives.

CH18376Enhanced Activity in the Tosylation of Tolanophanes via Supramolecular HgCl2 Recognition

Saeed Rastgar, Hossein Reza Darabi 0000-0002-9872-6015, Leila Sobhani, Kioumars Aghapoor, Rohoullah Firouzi, Farshid Mohsenzadeh, Hamed Yaghobi and Farshad Jafary
pp. 608-613
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The self-activation of various tolanophanes by HgCl2 was investigated based on the tosylation of hosts. The results revealed that the rate acceleration of the tosylation of hosts is different and depends on the size of the cavity. The experimental data was supported by UV-vis spectroscopy titration and theoretical calculations

CH19333Antitumour and Antimetastatic Effects and Safety Profile of a New Magnesium(II)-Chrysin Complex

Juan J. Martínez Medina, Javier Rodríguez, Julia Mermot and Luciana G. Naso
pp. 614-626
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Due to the side effects of current chemotherapeutic agents, scientists have begun to consider the use of metal-flavonoid complexes in cancer treatment. Our magnesium(II)-chrysin complex behaves more as a cytotoxic agent than the free ligand on the A549 cell line and its antimetastatic effect is pronounced. Also, the compound displays no acute toxicity (Artemia salina test) and no mutagenic effect (Ames test).

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AEC surfactants have excellent properties, but they also have many shortcomings in their synthesis. We synthesised an AECE-Na surfactant similar in structure to AEC in a green and efficient method, and explored its compounding properties. This research will contribute to the development of polyfunctional surfactants and the surfactant formulation industry.

CH19539Synthesis and Properties of Maleic Acid Cholesteryl Monoester–Citric Acid Triester

Cailing Xie, Lisi Ba, Yuru Wei, Zeyi Shi and Li'e Jin 0000-0002-0242-8807
pp. 635-639
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A new maleic acid cholesteryl monoester–citric acid trimester containing three cholesterol units was synthesised, providing a novel route for the synthesis of liquid crystalline materials. The compound displayed good liquid crystalline behaviours and certain thermal stability. The presence of hydrogen bonds and the increased number of cholesterol units play an important role in the formation and stability of the mesophase.

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Three luminescent mononuclear CuI complexes with functionalized 6-cyano-2,2′-bipyridine chelating ligands have been successfully prepared and characterised. It is shown that the introduction of two methyl groups at the 4,4’-positions of the 6-cyano-2,2′-bipyridine leads to a blue shift of the emission and is favourable for markedly enhancing the luminescence properties.

CH19670An Expeditious Route for the Synthesis of Oxazepine Triazolo-β-Lactams through Intramolecular Metal-Free [3+2] Azide–Alkyne Cycloaddition

Ram N. Yadav 0000-0001-6094-3447, Sunena Chandra, Armando Paniagua, Md. Firoj Hossain and Bimal Krishna Banik 0000-0002-7873-9062
pp. 654-657
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A facile metal-free intramolecular [3 + 2] cycloaddition reaction on a stereo-defined prebuilt β-lactam template for the synthesis of tricyclic oxazepane triazole β-lactam scaffolds has been achieved. The resulting unique tricyclic skeleton is presumably difficult to achieve by other existing methods. This synthetic protocol is circumvents the dominance of the copper-catalyzed click reaction.

CH20071Dendronised Polymers as Templates for In Situ Quantum Dot Synthesis

Alaa M. Munshi, Jessica A. Kretzmann 0000-0002-8680-7766, Cameron W. Evans 0000-0003-2312-9803, Anna M. Ranieri 0000-0002-4612-2121, Zibeon Schildkraut, Massimiliano Massi 0000-0001-6949-4019, Marck Norret 0000-0001-7540-1368, Martin Saunders 0000-0001-6873-7816 and K. Swaminathan Iyer 0000-0001-9329-4930
pp. 658-663
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This paper describes the synthesis of green and yellow CdTe QD–dendronised polymer nanocomposites in situ using a partially thiolated dendronised polymer as capping agent and stabiliser.

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