Preparation and Characterization of the Dicarbon Cluster Complex Ru5(μ5-C2)(μ5-SMe)2(μ-PBu2)2(CO)11
CJ Adams and MI Bruce
Australian Journal of Chemistry
49(4) 517 - 520
Published: 1996
Abstract
The preparation of the bis -tertiary phosphine C2(Pbu2)2 ( dpba ) is described. Pyrolysis of the ruthenium carbonyl derivative {Ru3(CO)11}2(μ- dbpa ) gives Ru5(μ5-C2PBu2)(μ-PBu2)(CO)13[in 41% overall yield from Ru3(CO)12)] which in turn reacts with Me2S2 to give Ru5(μ5-C2)(μ5-SMe)2(μ-PBu2)2(CO)11(19%).
https://doi.org/10.1071/CH9960517
© CSIRO 1996
