Register      Login
Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Organolead(IV) Tricarboxylates, New Reagents for Organic Synthesis

JT Pinhey

Australian Journal of Chemistry 44(10) 1353 - 1382
Published: 1991

Abstract

Aryl-, vinyl- and alk-1-ynyl-lead(IV) tricarboxylates act as electrophilic arylating, vinylating and alkynylating agents, respectively, with a variety of nucleophiles, especially soft carbon nucleophiles such as β- dicarbonyl compounds, phenols and nitroalkanes. In their reactions, they show a marked preference for carbon-carbon bond formation, especially in which a quaternary centre is produced. The formation and the synthetically useful reactions of these new reagents are reviewed.

https://doi.org/10.1071/CH9911353

© CSIRO 1991

Committee on Publication Ethics


Export Citation Get Permission

View Dimensions