The Two-Step Hydrolysis of Dimethoxo(tetraphenylporphyrinato)tin(IV)
HJ Lin, HJ Lin, JH Chen, JH Chen, LP Hwang and LP Hwang
Australian Journal of Chemistry
44(5) 747 - 751
Published: 1991
Abstract
The hydrolysis of dimethoxo ( tetraphenylporphyrinato )tin(IV), Sn ( tpp )( OMe )2 was studied by n.m.r. spectroscopy. The use of specially dehydrated CDCl3 allowed the hydrolysis intermediate hydroxomethoxo (tetraphenylporphyrinato )tin(IV) Sn ( tpp )( OMe )(OH), to be identified. The results show that the second step, of the two-step hydrolysis, is rate limiting.
https://doi.org/10.1071/CH9910747
© CSIRO 1991
