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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

MoO(S2)(S2CNR2)2 Complexes (R = Me, Et, Pr, Bu): Improved Syntheses and Thermogravimetric and Nuclear Magnetic Resonance Studies

XF Yan and CG Young

Australian Journal of Chemistry 44(3) 361 - 367
Published: 1991

Abstract

The reactions of MoO (S2CNR2)2 [R=Me, Et, Pr, Bu; formed in situ from the reactions of cis-MoO2(S2CNR2)2 and PR′3 (R′= Ph, Bu)] and propylene sulfide in 1,2-dichloroethane (for R = Me) or dichloromethane (others) constitute convenient, high-yield syntheses for the blue, seven-coordinate complexes MoO (S2)(S2CNR2)2 The complexes have been characterized by elemental analysis, infrared, electronic and 1H and 13C n.m.r. spectroscopy, and mass spectrometry. Thermogravimetric analyses indicate decomposition of the complexes to Mo2O2(μ-S)2(S2CNR2)2 at temperatures greater than 160°C.

https://doi.org/10.1071/CH9910361

© CSIRO 1991

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