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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Reactions of 1,4-Dimethyl-4-nitro-cyclohexa-2,5-dien-1-yl Acetates With Nitrogen Dioxide; the Formation of Polynitro Cyclohexenyl Esters

AD Abell, MP Hartshorn, ME Maclennan, WT Robinson and GJ Wright

Australian Journal of Chemistry 44(1) 43 - 51
Published: 1991

Abstract

Reactions of the epimeric 4-nitrocyclohexa-2,5-dienyl acetates (10) and (11) with nitrogen dioxide in acetic anhydride give closely similar mixtures of the nitro aromatic compounds (12)-(15), three polynitro nitrate esters (16)-(18), and two polynitro acetates (19) and (20). X-Ray crystal structure determinations are reported for compounds (16)-(18).

https://doi.org/10.1071/CH9910043

© CSIRO 1991

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