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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

New Methods for the Synthesis of Troponoid Compounds

MG Banwell

Australian Journal of Chemistry 44(1) 1 - 36
Published: 1991

Abstract

The ring expansion of 7-halogenobicyclo[4.1.0] heptenones and related compounds provides a useful new method for the preparation of the seven-membered conjugated carbocyclic compounds known as tropones and tropolones. This methodology has been exploited in the synthesis of various biologically active troponoid natural products including nezukone, the thujaplicins, thujaplicinol, MY3-469 and colchicine.

https://doi.org/10.1071/CH9910001

© CSIRO 1991

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