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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Preparation and Molecular Structures of FcC ≡ CI and {Co2(CO)6}2(µ:µ-FcC2C2Fc) [Fc = Ferrocenyl, (h-C5H4)Fe(h-C5H5)]

Michael I. Bruce, Brian W. Skelton, Mark E. Smith and Allan H. White

Australian Journal of Chemistry 52(6) 431 - 436
Published: 1999

Abstract

Iodination of FcC ≡ CH with morpholinium iodide gave structurally characterized iodoethynylferrocene, FcC ≡ CI; its reaction with Co2(CO)8 affords {Co2(CO)6}2(µ:µ-FcC2C2Fc), also characterized by an X-ray structure determination. This compound is formed by deiodinative coupling of the iodoalkyne and subsequent addition of a Co2(CO)6 group to each C ≡ C triple bond in the resulting diyne.

https://doi.org/10.1071/CH99024

© CSIRO 1999

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