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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A Single-Crystal X-Ray Analysis of a Novel Intramolecular Hydrogen-Bonded Biphenyl Phosphorane

AD Abell, KB Morris and V Mckee

Australian Journal of Chemistry 43(4) 765 - 771
Published: 1990

Abstract

An X-ray crystal structure and 1H n.m.r. analysis of the biphenyl phosphorane (4a) has revealed the presence of an intramolecular hydrogen bond resulting in an unusual biphenyl with a bridge forming a nine- membered ring. The related biphenyl phosphorane (4b) exists as two diastereoisomers.

https://doi.org/10.1071/CH9900765

© CSIRO 1990

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