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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Nitrones and Oxaziridines. XXXVII. Some Oxidation Reactions of 1-Pyrroline 1-Oxides

DSC Black and RJ Strauch

Australian Journal of Chemistry 41(2) 183 - 193
Published: 1988

Abstract

The 2,4-diaryl-1-pyrroline 1-oxides (4) can be converted into the related 2H-pyrrole 1-oxides (5) by treatment with N-bromosuccinimide and anhydrous potassium carbonate. Similar treatment of the 1-pyrroline 1-oxide (6) yielded the succinimido-substituted pyrroline (7). Selenium dioxide oxidation of the tetramethyl nitrone (8) under various conditions gave mixtures containing the compounds (10)-(12). Neither process provides a general conversion of 1-pyrroline 1-oxides into 2H-pyrrole 1-oxides.

https://doi.org/10.1071/CH9880183

© CSIRO 1988

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