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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Experiments Directed Towards the Synthesis of Anthracyclinones .XIV. An Intermediate for the Synthesis of Vineomycins

RC Cambie, TA Howe, MG Pausler, PS Rutledge and PD Woodgate

Australian Journal of Chemistry 40(6) 1063 - 1072
Published: 1987

Abstract

Anthrarufin (4) has been converted by a high-yielding route involving sequential reductive Claisen rearrangements into 1-acetoxy-5-methoxy-9,10-dioxo-6-(2'-oxopropy1)-9,10-dihydroanthracene-2-carbaldehyde (3), an intermediate which is suitable for the synthesis of vineomycins . The thermal Claisen rearrangements of some allyl ethers of 1,5-dihydroxyanthraquinone have been examined.

https://doi.org/10.1071/CH9871063

© CSIRO 1987

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