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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Treatment of Some Cyclic Thiocarbonates With Methyl Halide/Propylene Oxide

JJ Patroni and RV Stick

Australian Journal of Chemistry 40(5) 795 - 802
Published: 1987

Abstract

Treatment of thiocarbonates (OCSO) with methyl iodidelpropylene oxide at 80º can lead smoothly to the carbonate. In some cases, a competing process is the formation of iodo thiocarbonates ( OCOSMe ), and an explanation is provided for the product distributions observed. The corresponding reactions with methyl bromide and methyl chloride (as methyl chloroformate ) are much less efficient.

https://doi.org/10.1071/CH9870795

© CSIRO 1987

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