Metal Template Reactions. XXIV. Synthesis of Macrocyclic Amide and Ester Complexes Via Substituted 1,1'-Oxalylbisisatins and the Deesterification of Some Ester Complexes
DS Black and GI Moss
Australian Journal of Chemistry
40(1) 143 - 155
Published: 1987
Abstract
The 5-substituted phenylglyoxylic esters (3) and amides (4) have been prepared via the corresponding 1,1′-oxalylbisisatins (2). The nickel(11) macrocyclic amide complexes (7) have been prepared but the related ester complexes (5) were found to undergo deesterification (hydrolysis and decarboxylation) to provide a convenient route to the proto-complexes (6).
https://doi.org/10.1071/CH9870143
© CSIRO 1987
