N.M.R. Studies of Phosphine Adducts of Mercury and Cadmium Xanthates and Halo Xanthates: Crystal and Molecular Structures of Cd(S2COPri)2PPh3, Hg(S2COPrI)2PPh3 and Hg(S2COPrI)2p(c-C6H11)3

BF Abrahams; M Corbett; D Dakternieks; RW Gable; BF Hoskins; ERT Tiekink; G Winter

doi:10.1071/ch9861993

RESEARCH ARTICLE

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N.M.R. Studies of Phosphine Adducts of Mercury and Cadmium Xanthates and Halo Xanthates: Crystal and Molecular Structures of Cd(S₂COPrⁱ)₂PPh₃, Hg(S₂COPr^I)₂PPh₃ and Hg(S₂COPr^I)₂p(c-C₆H₁₁)₃

BF Abrahams, M Corbett, D Dakternieks, RW Gable, BF Hoskins, ERT Tiekink and G Winter

Australian Journal of Chemistry 39(12) 1993 - 2001
Published: 1986

Abstract

Phosphorus-31, cadmium-113 and mercury-199 n.m.r. techniques have been used to study adduct formation, in solution, between phosphines and cadmium and mercury xanthates and halo xanthates. The crystal structures of the 1:1 phosphine adducts Cd (S₂COPrⁱ)₂PPh₃, Hg(S₂COPrⁱ)₂PPh₃ and Hg(S₂COPrⁱ)₂P(c-C₆H₁₁)₃ have been determined.

https://doi.org/10.1071/CH9861993

N.M.R. Studies of Phosphine Adducts of Mercury and Cadmium Xanthates and Halo Xanthates: Crystal and Molecular Structures of Cd(S2COPri)2PPh3, Hg(S2COPrI)2PPh3 and Hg(S2COPrI)2p(c-C6H11)3

Abstract

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N.M.R. Studies of Phosphine Adducts of Mercury and Cadmium Xanthates and Halo Xanthates: Crystal and Molecular Structures of Cd(S₂COPrⁱ)₂PPh₃, Hg(S₂COPr^I)₂PPh₃ and Hg(S₂COPr^I)₂p(c-C₆H₁₁)₃