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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Chiral induction in the addition of the anion from 3-(p-Methylbenzenesulfinyl)prop-1-ene with substituted benzaldehydes

DD Ridley and MA Smal

Australian Journal of Chemistry 36(5) 1049 - 1055
Published: 1983

Abstract

Addition of the anion from 3-(p-methylbenzenesu1finyl)prop-1-ene to substituted benzaldehydes affords mixtures of α- and γ-products. The diastereoisomeric ratios. which were determined by 1H n.m.r. spectroscopy, appeared relatively independent of electronic factors. Possible transition state models to account for the stereochemical aspects of the reaction are discussed.

https://doi.org/10.1071/CH9831049

© CSIRO 1983

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