Gas-phase pyrolysis of isopropyl chloroformate
RL Johnson and VR Stimson
Australian Journal of Chemistry
35(4) 849 - 852
Published: 1982
Abstract
Homogeneous, molecular elimination of propene from isopropyl chloroformate takes place at 229-277ºC with rate
ke = 1013.94exp(-174000/8.314T) s-1
Rate comparisons indicate that a polar transition state is involved.
https://doi.org/10.1071/CH9820849
© CSIRO 1982