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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Intermolecular interactions in water + acetonitrile mixtures : Evidence from the composition variation of solvent polarity parameters

S Balakrishnan and AJ Easteal

Australian Journal of Chemistry 34(5) 943 - 947
Published: 1981

Abstract

The dependence on composition of the polarity of H2O+MeCN mixtures has been determined from measurements of the empirical solvent polarity parameter ET. ET has been found to vary with composition in a similar fashion to that which has been reported previously for most other H2O+non-electrolyte mixtures for which ET data are available. The variation of ET with composition is interpreted in terms of the Naberukhin-Rogov structural model for H2O+nonelectrolyte mixtures.

https://doi.org/10.1071/CH9810943

© CSIRO 1981

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