Contributions from dielectric inhomogeneity to the free energy of ionic solvation
PJ Stiles
Australian Journal of Chemistry
33(6) 1389 - 1391
Published: 1980
Abstract
A new dielectric profile for the solvent dielectric constant beyond the primary coordination or solvation sphere is used to show that neglect of dielectric inhomogeneity by the Born treatment can lead to significant overestimation of ionic solvation energies.
https://doi.org/10.1071/CH9801389
© CSIRO 1980
