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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

17,18-Cyclo Steroids

P Bogan and RE Gall

Australian Journal of Chemistry 32(10) 2323 - 2326
Published: 1979

Abstract

3α-Acetoxy-5β-pregnan-20β-ol (4a) has been converted into the iodo alcohol (6) with lead tetraacetate and iodine. The derived iodo ketone (7) gave good yields of 3α-acetoxy-17,18-cyclo-5β- pregnan-20-one(8a) when treated immediately with potassium t-butoxide and t-butyl alcohol.

https://doi.org/10.1071/CH9792323

© CSIRO 1979

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