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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Crystal Structure of Tetraisothiocyanato-tetrakis(trimethylphosphine oxide)uranium(IV)

CEF Rickard and DC Woollard

Australian Journal of Chemistry 32(10) 2181 - 2185
Published: 1979

Abstract

The structure of the title compound has been determined by single-crystal X-ray crystallography. The crystals are orthorhombic, a 12·122(1), b 12·545(2), c 22·128(3) Å, space group Pccn. The structure was refined to a final residual of 0·040,1565 structure amplitudes being used. The molecules are eight-coordinate, the coordination polyhedron being an almost regular square antiprism, with the thiocyanate groups bonded through nitrogen.

https://doi.org/10.1071/CH9792181

© CSIRO 1979

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