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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Interconversion of Two Elemadienolides Through Two Consecutive Cope Rearrangements

DJ Brecknell and RM Carman

Australian Journal of Chemistry 32(9) 2097 - 2102
Published: 1979

Abstract

Callitrin (1) at 220º partly isomerizes to epicallitrin (9). This result, together with those of the Cope rearrangements of some other sesquiterpenoids, is explained in terms of the accessibility of suitable transition states and the relative stabilities of the possible products.

https://doi.org/10.1071/CH9792097

© CSIRO 1979

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