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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Reactions of titanium(IV) chloride with formic acid

RC Paul, RC Kumar, OB Baidya and R Kapoor

Australian Journal of Chemistry 31(2) 425 - 429
Published: 1978

Abstract

Titanium(IV) chloride reacts with formic acid to give the disubstituted product, Cl2Ti(OOCH)2, at low temperatures and the hydrolysed product (OH)2Ti(OOCH)2 at higher temperatures. These compounds have been characterized by elementary analysis, infrared and thermal measurements. The possibility of these solvolysed products acting as Lewis acids has also been explored.

https://doi.org/10.1071/CH9780425

© CSIRO 1978

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