The effect of solvent on the barrier to internal rotation in p-substituted nitrosoanilines
AR Furness, PD Buckley and KW Jolley
Australian Journal of Chemistry
28(10) 2303 - 2306
Published: 1975
Abstract
The solvent dependence of the barrier to internal rotation about the Ar-NO bond in N,N-dimethyl-p-nitrosoaniline and N,N-diethyl-p- nitrosoaniline has been investigated by a complete N.M.R. line-shape method. Activation parameters are reported for the nitrosoanilines in solution in acetone[D6], chloroform[D], and toluene[D8]. The effect of solvent has been found to be small.https://doi.org/10.1071/CH9752303
© CSIRO 1975