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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The effect of solvent on the barrier to internal rotation in p-substituted nitrosoanilines

AR Furness, PD Buckley and KW Jolley

Australian Journal of Chemistry 28(10) 2303 - 2306
Published: 1975

Abstract

The solvent dependence of the barrier to internal rotation about the Ar-NO bond in N,N-dimethyl-p-nitrosoaniline and N,N-diethyl-p- nitrosoaniline has been investigated by a complete N.M.R. line-shape method. Activation parameters are reported for the nitrosoanilines in solution in acetone[D6], chloroform[D], and toluene[D8]. The effect of solvent has been found to be small.

https://doi.org/10.1071/CH9752303

© CSIRO 1975

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