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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Eight-coordinate complexes of titanium and niobium tetrachlorides with 1,8- Bisdimethylarsinonaphthalene

DL Kepert and KR Trigwell

Australian Journal of Chemistry 28(6) 1245 - 1248
Published: 1975

Abstract

Titanium and niobium tetrachlorides form the eight-coordinate adducts [TiCl4(naars)2] and[NbCl4(naars)2] with 1,8-bisdimethylarsinonaphthalene. The visible spectrum of the latter compound shows that as a result of the small ?bite? of this bidentate ligand, the order of orbital energies is dxy < dxz, dyz < dx2-y2 < dz2.

https://doi.org/10.1071/CH9751245

© CSIRO 1975

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