N.M.R. studies of ligand exchange on acetylacetonatotrimethylplatinum(IV)
NS Ham, JR Hall and GA Swile
Australian Journal of Chemistry
28(4) 759 - 761
Published: 1975
Abstract
A quantitative analysis of the variable-temperature 1H N.M.R. spectra of acetylacetonatotrimethyl-platinum(IV) has been made. In CDCl3 solution the exchange of acetylacetonate ligands is a first-order reaction and proceeds predominantly by dissociation of the dimer into two separated five-coordinate activated complexes. The activation energy is 61.5 ± 0.8 kJ mol-1.https://doi.org/10.1071/CH9750759
© CSIRO 1975
