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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

2-Aminothiazole, acetylaminothiazole, dimethylhydantoin and thiohydantoin complexes of tin(IV) and titanium(IV) halides

PP Singh and UP Shukla

Australian Journal of Chemistry 27(8) 1827 - 1832
Published: 1974

Abstract

Complexes of the type MX4L2 (M = Sn, Ti; X = Cl, Br, I; L = dimethylhydantoin, thiohydantoin, 2-aminothiazole and 2-acetylaminothiazole) have been prepared and characterized. Infrared spectral studies indicate exocyclic nitrogen of 2:aminothiazole and carbonyl oxygen of all other ligands as the donor site. Far-infrared spectra suggest that dimethylhydantoin and 2-acetylaminothiazole complexes are trans, and 2-aminothiazole and thiohydantoin complexes are cis octahedral.

https://doi.org/10.1071/CH9741827

© CSIRO 1974

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