Activation of saturated hydrocarbons by homogeneous metal catalysts : Deuterium exchange in iridium(III) solution
JL Garnett, MA Long and KB Peterson
Australian Journal of Chemistry
27(8) 1823 - 1825
Published: 1974
Abstract
Isotopic hydrogen exchange between simple alkanes and D2O is homogeneously catalysed by sodium chloroiridite at 160°C. Initial isotope orientation favours hydrogen on the primary carbon atoms.High M values for the exchange are typical.https://doi.org/10.1071/CH9741823
© CSIRO 1974