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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Activation of saturated hydrocarbons by homogeneous metal catalysts : Deuterium exchange in iridium(III) solution

JL Garnett, MA Long and KB Peterson

Australian Journal of Chemistry 27(8) 1823 - 1825
Published: 1974

Abstract

Isotopic hydrogen exchange between simple alkanes and D2O is homogeneously catalysed by sodium chloroiridite at 160°C. Initial isotope orientation favours hydrogen on the primary carbon atoms.High M values for the exchange are typical.

https://doi.org/10.1071/CH9741823

© CSIRO 1974

Committee on Publication Ethics

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