Substituted carbonyl derivatives of the Group VI transition metals. V. Complexes with tolyl-substituted Bis(diphenylarsino)methane ligands

Abstract

Ligands of the type bis(ditoly1arsino)methane have been synthesized and their derivatives with hexacarbonylmolybdenum(0) prepared. Nuclear magnetic resonance and infrared spectroscopy have been used to determine the stereochemistry of the complexes and also to study steric effects within the molecules.